This is why there's only one launch window per day to launch to the ISS from KSC. From a physics perspective it's possible to launch either north or south to reach the ISS at 51.6° which would be two launch windows per day, but KSC must launch north to avoid overflying populated areas to the south.If Canaveral is far enough to overfly Cuba (and apparently it is) - Boca Chica certainly is.
For Boca Chica it has to thread the needle between Cuba and Florida so there's only the one choice. This means they can't launch to the ISS or launch their broadband satellites from Boca Chica.